SYNTHESIS AND CHARACTERIZATION OF THE FULLERENE CO-CRYSTALS C-60-CENTER-DOT-12C(6)H(12), C-70-CENTER-DOT-12C(6)H(12), C-60-CENTER-DOT-12CCL(4), C-60-CENTER-DOT-2CHBR(3), C-60-CENTER-DOT-2CHCL(3), C-60-CENTER-DOT-2H(2)CCL(2)

被引:37
作者
JANSEN, M
WAIDMANN, G
机构
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 01期
关键词
FULLERENE C-60; C-70; CRYSTALLIZATION FROM NONPOLAR SOLVENTS; CHARACTERIZATION OF CO-CRYSTALS;
D O I
10.1002/zaac.19956210105
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
By crystallization of fullerenes from non-polar solvents (C6H12, CCl4, CHBr3, CHCl3 H2CCl2) compounds of the following compositions were obtained: C-60 (.) 12C(6)H(12), C-70 (.) 12C(6)H(12), C-60 (.) 12CCl(4), C-60 (.) 2CHCl(3), C-60 (.) 2CHBr(3) and C-60 (.) 2H(2)CCl(2). Lattice parameters have been determined by X-ray diffraction of powder samples; according to single-crystal examinations on C-60 (.) 12C(6)H(12), C-60 (.) 12CCl(4) and C-60 (.) 2CHBr(3) the fullerene is orientationally disordered. C-60 (.) 12C(6)H(12), kubisch, a = 28,167(1) Angstrom; C-70 (.) 12C(6)H(12), kubisch, a = 28,608(2) Angstrom; C-60 (.) 12CCl(4), kubisch, a = 27,42(1) Angstrom; C-60 (.) 2CHBr(3), hexagonal, a=10,212(1), c=10,209(1) Angstrom; C-60 (.) 2CHCl(3), hexagonal, a=10,08(1), c=10,11(2) Angstrom;C-60 (.) 2H(2)CCl(2), tetragonal, a=16,400(1) Angstrom, c=11,645(7) Angstrom.
引用
收藏
页码:14 / 18
页数:5
相关论文
共 18 条
  • [1] ELECTROCRYSTALLIZATION AND CRYSTAL-STRUCTURE DETERMINATION OF PH(4)PC(60)CENTER-DOT-PH(4)PCL
    BILOW, U
    JANSEN, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) : 403 - 404
  • [2] PREPARATION AND C-13 NMR SPECTROSCOPIC CHARACTERIZATION OF C-60CL6
    BIRKETT, PR
    AVENT, AG
    DARWISH, AD
    KROTO, HW
    TAYLOR, R
    WALTON, DRM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) : 1230 - 1232
  • [3] PREPARATION AND CHARACTERIZATION OF C60BR6 AND C60BR8
    BIRKETT, PR
    HITCHCOCK, PB
    KROTO, HW
    TAYLOR, R
    WALTON, DRM
    [J]. NATURE, 1992, 357 (6378) : 479 - 481
  • [4] Burgi H.-B., 1992, ANGEW CHEM-GER EDIT, V104, P667
  • [5] SOLVATED C60 AND C60/C70 AND THE LOW-RESOLUTION SINGLE-CRYSTAL X-RAY STRUCTURE OF C60
    GORUN, SM
    CREEGAN, KM
    SHERWOOD, RD
    COX, DM
    DAY, VW
    DAY, CS
    UPTON, RM
    BRIANT, CE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) : 1556 - 1558
  • [6] CRYSTAL-STRUCTURE OF OSMYLATED C60 - CONFIRMATION OF THE SOCCER BALL FRAMEWORK
    HAWKINS, JM
    MEYER, A
    LEWIS, TA
    LOREN, S
    HOLLANDER, FJ
    [J]. SCIENCE, 1991, 252 (5003) : 312 - 313
  • [7] SUPERCONDUCTIVITY AT 18-K IN POTASSIUM-DOPED C-60
    HEBARD, AF
    ROSSEINSKY, MJ
    HADDON, RC
    MURPHY, DW
    GLARUM, SH
    PALSTRA, TTM
    RAMIREZ, AP
    KORTAN, AR
    [J]. NATURE, 1991, 350 (6319) : 600 - 601
  • [8] SOLID C-60 - A NEW FORM OF CARBON
    KRATSCHMER, W
    LAMB, LD
    FOSTIROPOULOS, K
    HUFFMAN, DR
    [J]. NATURE, 1990, 347 (6291) : 354 - 358
  • [9] C-60 - BUCKMINSTERFULLERENE
    KROTO, HW
    HEATH, JR
    OBRIEN, SC
    CURL, RF
    SMALLEY, RE
    [J]. NATURE, 1985, 318 (6042) : 162 - 163
  • [10] LIU S, 1991, SCIENCE, V252, P408