ENHANCEMENT OF ENANTIOCONTROL DIASTEREOCONTROL IN CATALYTIC INTRAMOLECULAR CYCLOPROPANATION AND CARBON-HYDROGEN INSERTION REACTIONS OF DIAZOACETATES WITH RH-2(4S-MPPIM)(4)

被引：73

作者：

DOYLE, MP

ZHOU, QL

DYATKIN, AB

RUPPAR, DA

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 42期

关键词：

D O I：

10.1016/0040-4039(95)01561-U

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dirhodium(II) tetrakis[methyl 1-(3-phenylpropanoyl)imidazolidin-2-one-4(S)-carboxylate], Rh-2(4S-MPPIM)(4), provides significant enhancement in enantiocontrol for intramolecular cyclopropanation reactions of allylic diazoacetates and optimal enantiocontrol/diastereocontrol for intramolecular C-H insertion reactions of secondary alkyl diazoacetates.

引用

页码：7579 / 7582

页数：4

共 12 条

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