ENHANCEMENT OF ENANTIOCONTROL DIASTEREOCONTROL IN CATALYTIC INTRAMOLECULAR CYCLOPROPANATION AND CARBON-HYDROGEN INSERTION REACTIONS OF DIAZOACETATES WITH RH-2(4S-MPPIM)(4)

被引:73
作者
DOYLE, MP
ZHOU, QL
DYATKIN, AB
RUPPAR, DA
机构
[1] Department of Chemistry, Trinity University, San Antonio
关键词
D O I
10.1016/0040-4039(95)01561-U
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dirhodium(II) tetrakis[methyl 1-(3-phenylpropanoyl)imidazolidin-2-one-4(S)-carboxylate], Rh-2(4S-MPPIM)(4), provides significant enhancement in enantiocontrol for intramolecular cyclopropanation reactions of allylic diazoacetates and optimal enantiocontrol/diastereocontrol for intramolecular C-H insertion reactions of secondary alkyl diazoacetates.
引用
收藏
页码:7579 / 7582
页数:4
相关论文
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