A CONCISE SYNTHESIS OF (-)-CONDURITOL-F FROM L-QUEBRACHITOL VIA ALCL3-NORMAL-BU4NI MEDIATED DEMETHYLATION

被引：43

作者：

AKIYAMA, T

SHIMA, H

OZAKI, S

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama, 790, Bunkyo-cho

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

(-)-CONDURITOL-F; (+)-CONDURITOL-B; L-QUEBRACHITOL; DEMETHYLATION; ALCL3;

D O I：

10.1016/0040-4039(91)80092-K

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(-)-Conduritol F was prepared starting from naturally occurring cyclitol, L-quebrachitol, in 5 steps via AlCl3-Bu4NI mediated chemoselective demethylation of the methyl ether. A preparation of (+)-conduritol B was also described.

引用

页码：5593 / 5596

页数：4

共 27 条

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