HALOGENATION AND ACYLOXYLATION OF N-CYCLOHEX-2-EN-1-ON-3-YL-AMINO ACIDS

被引：4

作者：

HABERMEHL, GG

WIPPERMANN, I

KREBS, HC

DIECK, ST

机构：

[1] Chemisches Institut der Tierärztlichen Hochschule Hannover, D-3000, Hannover

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 10期

关键词：

ACYLOXYLATIONS; ENAMINONES (SEC);

D O I：

10.1515/znb-1991-1020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Secondary enaminones 2 are easily halogenated to yield the so far unknown halogenides 3, 4 and 5. Acyloxylation of enaminones 2 by dibenzoylperoxide leads to benzoyloxylated substances 13, which also have not been described jet. Bisacylated products could not be traced. Only the rearranged compounds 14 could be isolated. 14b showed cytotoxic activity.

引用

页码：1415 / 1420

页数：6

共 11 条

[1] INTRODUCTION OF OXYGEN FUNCTIONS INTO THE ALPHA-POSITION OF BETA-DIKETONES .1. ACYLOXYLATION OF 3-SEC-AMINO-2-CYCLOHEXEN-1-ONES BY MEANS OF DIACYL PEROXIDES [J].