ELECTROCHEMISTRY OF POTENTIAL BIOREDUCTIVE ALKYLATING QUINONES .2. ELECTROCHEMICAL PROPERTIES OF 2,5-BIS(1-AZIRIDINYL)-3,6-BIS(ETHOXYCARBONYLAMINO)-1,4-BENZOQUINONE AND SOME MODEL COMPOUNDS

被引：26

作者：

DRIEBERGEN, RJ ^{[1
]}

HOLTHUIS, JJM ^{[1
]}

BLAUW, JS ^{[1
]}

KELDER, SJP ^{[1
]}

VERBOOM, W ^{[1
]}

REINHOUDT, DN ^{[1
]}

VANDERLINDEN, WE ^{[1
]}

机构：

[1] UNIV TWENTE,DEPT CHEM TECHNOL,7500 AE ENSCHEDE,NETHERLANDS

来源：

ANALYTICA CHIMICA ACTA | 1990年 / 234卷 / 02期

关键词：

Aziridinylquinones; Bis(1-aziridinyl)bis(ethoxycarbonylamino)-benzoquinone; Controlled potential electrolysis; Quinones;

D O I：

10.1016/S0003-2670(00)83570-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The reduction mechanism of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (Diaziquone, AZQ) and several model compounds of the mono- and bis(1-aziridinyl)quinone type at the dropping mercury electrode in aqueous solutions was studied. In addition, the influence of methyl substitution of the aziridinyl moiety at the 2-position on the protonation of the aziridine nitrogen was investigated. Substituent effects on quinone reduction and aziridine protonation prior to and following quinone reduction were studied qualitatively. © 1990.

引用

页码：285 / 307

页数：23

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