4-COORDINATE COPPER(I) IODIDE COMPLEXES WITH TRIPHENYLPHOSPHINE AND HETEROCYCLIC THIONE LIGANDS - THE CRYSTAL-STRUCTURE OF [CU(PPH3)2(PYMTH)I]

被引：51

作者：

ASLANIDIS, P ^{[1
]}

HADJIKAKOU, SK ^{[1
]}

KARAGIANNIDIS, P ^{[1
]}

GDANIEC, M ^{[1
]}

KOSTURKIEWICZ, Z ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV POZNAN,DEPT CRYSTALLOG,PL-61712 POZNAN,POLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 18期

关键词：

D O I：

10.1016/S0277-5387(00)88260-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Cu(PPh3)I]4 reacts with heterocyclic thiones (L) [L = pyrimidine-2-thione (pymtH), 1,3-thiazoline-2-thione (tzdtH), 1,3-imidazoline-2-thione (imtH), benz-1,3-imidazoline-2-thione (bzimtH-2) and benz-1,3-thiazoline-2-thione (bztztH)] in the presence of triphenylphosphine to give mononuclear complexes of the general formula [Cu(PPh3)2 (L)I]. These complexes have been characterized by various physicochemical methods. The crystal structure of [Cu(PPh3)2(pymtH)I] has been determined by single-crystal X-ray diffraction methods. The molecule is mononuclear, with a distorted tetrahedral geometry and bond lengths Cu-S = 2.338(4), Cu-I = 2.674(2), Cu-P = 2.296(4) and 2.303(4) angstrom.

引用

页码：2221 / 2226

页数：6

共 32 条

[21] SYNTHESIS AND CHARACTERIZATION OF COPPER(I) HALIDE-COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF COPPER(I) 1-METHYL-1,3-IMIDAZOLINE-2-THIONE BIS(TRIPHENYLPHOSPHINE)BROMIDE, [CU(PPH3)2(MEIMTH)BR] [J].

KARAGIANNIDIS, P ;

ASLANIDIS, P ;

PAPASTEFANOU, S ;

MENTZAFOS, D ;

HOUNTAS, A ;

TERZIS, A .

POLYHEDRON, 1990, 9 (07) :981-986

[22] COPPER(I) BROMIDE COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF COPPER(I) PYRIMIDINE-2-THIONE BIS (TRIPHENYLPHOSPHINE) BROMIDE [CU(PPH3)2(PYMTH)BR] [J].

LECOMTE, C ;

SKOULIKA, S ;

ASLANIDIS, P ;

KARAGIANNIDIS, P ;

PAPASTEFANOU, S .

POLYHEDRON, 1989, 8 (08) :1103-1109

[23] METHOD FOR LOCATION OF PEAKS IN STEP-SCAN-MEASURED BRAGG-REFLECTIONS [J].

LEHMANN, MS ;

LARSEN, FK .

ACTA CRYSTALLOGRAPHICA SECTION A, 1974, A 30 (JUL1) :580-584

[24] STRUCTURE OF BIS(MU-PYRIDINE-2-THIONE-MU-S)-BIS[IODO(PYRIDINE-2-THIONE-S)COPPER(I)] [J].

MENTZAFOS, D ;

TERZIS, A ;

KARAGIANNIDIS, P ;

ASLANIDIS, P .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :54-56

[25] SOLUTION STRUCTURE OF COINAGE METAL-PHOSPHINE COMPLEXES [J].

MUETTERTIES, EL ;

ALEGRANTI, CW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (13) :4114-+

[26] THE C=S STRETCHING FREQUENCY AND THE -N-C=S BANDS IN THE INFRARED [J].

RAO, CNR ;

VENKATARAGHAVAN, R .

SPECTROCHIMICA ACTA, 1962, 18 (04) :541-547

[27] COMPLEXES OF HETEROCYCLIC THIONE DONORS [J].

RAPER, ES .

COORDINATION CHEMISTRY REVIEWS, 1985, 61 (JAN) :115-184

[28] COMPLEXES OF 1-METHYLIMIDAZOLINE-2-THIONE WITH CO(II) AND ZN(II) HALIDES AND PERCHLORATES [J].

RAPER, ES ;

BROOKS, JL .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (12) :2163-2166

[29] FLUORESCENT COPPER(I) COMPLEXES - CORRELATION OF STRUCTURAL AND EMISSION CHARACTERISTICS OF [(CUL(QUIN)2)2] AND [CU4I4(QUIN)4] (QUIN = QUINOLINE) [J].

RATH, NP ;

HOLT, EM ;

TANIMURA, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (11) :2303-2310

[30]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

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