Synthesis, properties and molecular structure of a new isomer of [2.(4)]-paracyclophanetetraene: (E,Z,E,Z)-[2.(4)]-paracyclophanetetraene

被引：15

作者：

Darabi, HR ^{[1
]}

Kawase, T ^{[1
]}

Oda, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 52期

关键词：

D O I：

10.1016/0040-4039(95)02065-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(E,Z,E,Z)-[2.(4)]-Paracyclophane is first obtained together with other isomers by the McMurry coupling of 4,4'-diformyl-(Z)-stilbene; an X-ray analysis of the new cyclophane shows an ellipsoidal structure with more strained (E)-stilbene skeleton than its tetrahydro compound.

引用

页码：9525 / 9526

页数：2

共 11 条

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