PALLADIUM-CATALYZED COUPLING OF VINYLFERROCENE WITH AROMATIC HALIDES - A HIGHLY EFFICIENT ROUTE TO (FERROCENYLVINYL)ARENES

被引：21

作者：

KONIG, B ^{[1
]}

ZIEG, H ^{[1
]}

BUBENITSCHEK, P ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38106 BRAUNSCHWEIG,GERMANY

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 09期

关键词：

VINYLFERROCENE; PALLADIUM-CATALYZED COUPLING; (FERROCENYLVINYL)ARENES;

D O I：

10.1002/cber.19941270935

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Ferrocenylvinyl)arenes 3, 5, and 7 are obtained from vinylferrocene (1) and substituted aromatic and heteroaromatic halides by palladium-catalyzed Heck-type reactions. Up to three ferrocene units are introduced in one step by the multifold reaction of 1,2-dibromo- (4) or 1,3,5-tribromobenzene (6) with 1. The first crystal structure of a bis(ferrocenylvinyl)benzene chromophore (5) is reported.

引用

页码：1811 / 1813

页数：3

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