DETERMINATION OF THE PHENYLUREA HERBICIDE LINURON AND ITS METABOLITES IN ENVIRONMENTAL-SAMPLES BY HPLC WITH SERIAL ULTRAVIOLET AND AMPEROMETRIC DETECTION

被引：16

作者：

HENZE, G ^{[1
]}

MEYER, A ^{[1
]}

HAUSEN, J ^{[1
]}

机构：

[1] UNIV TRIER,ANORGAN & ANALYT CHEM ABT,W-5500 TRIER,GERMANY

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1993年 / 346卷 / 6-9期

关键词：

D O I：

10.1007/BF00321287

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Procedures were developed for the determination of the herbicide linuron and its main metabolites using reversed-phase high performance liquid chromatography with serial ultraviolet-amperometric detection. For the application to water and soil analysis solid-phase extraction with cyclohexyl cartridges was found to be useful for the separation and enrichment of these compounds at trace level. By amperometric detection at + 1.3 V down to approximately 0.5 ng of the tested metabolites could be determined. This is about 5-times more sensitive than the ultraviolet detection by the selected wavelength of 247 nm. Only for linuron the UV-detection proved to be more sensitive under the described conditions; the detection limit was found to be 5 ng.

引用

页码：761 / 765

页数：5

共 23 条

[1] THE DETERMINATION OF UREA AND CARBAMATE HERBICIDES USING A WALL JET ELECTRODE [J].

ALBERY, WJ ;

FLEET, B ;

BRETT, AMO .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1984, 14 (04) :550-553

[2] DETERMINATION OF PHENYLUREA HERBICIDES VIA DIRECT DERIVATIZATION WITH HEPTAFLUOROBUTYRIC ANHYDRIDE [J].

BRINKMAN, UAT ;

DEKOK, A ;

GEERDINK, RB .

JOURNAL OF CHROMATOGRAPHY, 1984, 283 (JAN) :113-126

[3]

BRODESSER J, 1990, VOM WASSER, V74, P107

[4] RAPID METHOD FOR THE DETERMINATION OF ALACHLOR, ATRAZINE AND METOLACHLOR IN GROUNDWATER BY SOLID-PHASE EXTRACTION [J].

BROOKS, MW ;

JENKINS, J ;

JIMENEZ, M ;

QUINN, T ;

CLARK, JM .

ANALYST, 1989, 114 (03) :405-406

[5] A RAPID METHOD FOR THE SIMULTANEOUS ANALYSIS OF CHLORPYRIFOS, ISOFENPHOS, CARBARYL, IPRODIONE, AND TRIADIMEFON IN GROUNDWATER BY SOLID-PHASE EXTRACTION [J].

BROOKS, MW ;

TESSIER, D ;

SODERSTROM, D ;

JENKINS, J ;

CLARK, JM .

JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1990, 28 (09) :487-489

[6]

CAVERLY DJ, 1978, ANALYST, V103, P368, DOI 10.1039/an9780300368

[7] CHROMATOGRAPHIC DETERMINATION OF PHENYLUREA HERBICIDES AND THEIR CORRESPONDING ANILINE DEGRADATION PRODUCTS IN ENVIRONMENTAL-SAMPLES .1. [J].

DEKOK, A ;

VOS, YJ ;

VANGARDEREN, C ;

DEJONG, T ;

VANOPSTAL, M ;

FREI, RW ;

GEERDINK, RB ;

BRINKMAN, UAT .

JOURNAL OF CHROMATOGRAPHY, 1984, 288 (01) :71-89

[8]

DUNSCH L, 1973, Z CHEM, V13, P222

[9] PRE-COLUMN TECHNOLOGY IN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY FOR THE DETERMINATION OF PHENYLUREA HERBICIDES IN WATER IN THE PRESENCE OF THEIR ANILINES [J].

GOEWIE, CE ;

KWAKMAN, P ;

FREI, RW ;

BRINKMAN, UAT ;

MAASFELD, W ;

SESHADRI, T ;

KETTRUP, A .

JOURNAL OF CHROMATOGRAPHY, 1984, 284 (01) :73-86

[10]

HAUSEN J, 1992, THESIS KAISERSLAUTER

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