SYNTHESIS AND STRUCTURAL-ANALYSIS OF LONG-CHAIN N-ACETYL-N-ALKYLLACTOSYLAMINES, A NEW SERIES OF SURFACTANTS DERIVED FROM UNPROTECTED LACTOSE

被引：28

作者：

COSTES, F ^{[1
]}

ELGHOUL, M ^{[1
]}

BON, M ^{[1
]}

RICOLATTES, I ^{[1
]}

LATTES, A ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,IMRCP LAB,CNRS,UA 470,F-31062 TOULOUSE,FRANCE

来源：

LANGMUIR | 1995年 / 11卷 / 10期

关键词：

D O I：

10.1021/la00010a010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Surfactants based on sugars are very important for extraction of proteins. We describe here a new series of surfactants, the N-acetyl-N-alkyllactosylamines, easily prepared in a two-stage route starting from unprotected lactose. These new compounds have comparable surfactant activity to existing sugar-based homologs currently employed in the extraction of proteins from biological samples. Moreover, a complete structural analysis of these new nonionic amphiphiles by H-1 and C-13 NMR showed beta anomeric conformation suitable for chiral induction in micelles.

引用

页码：3644 / 3647

页数：4

共 15 条

[1] ON SOME PHYSICOCHEMICAL PROPERTIES OF SUCROSE ESTERS AND THE STABILITY THEY CONFER TO MEMBRANE-PROTEINS [J].

ABRAN, D ;

BOUCHER, F ;

HAMANAKA, T ;

HIRAKI, K ;

KITO, Y ;

KOYAMA, K ;

LEBLANC, RM ;

MACHIDA, H ;

MUNGER, G ;

SEIDOU, M ;

TESSIER, M .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1989, 128 (01) :230-236

[2]

AUVRAY X, IN PRESS

[3] GLYCOLIPID SELF-ASSEMBLY - MICELLAR STRUCTURE [J].

CECUTTI, C ;

FOCHER, B ;

PERLY, B ;

ZEMB, T .

LANGMUIR, 1991, 7 (11) :2580-2585

[4] MEMBRANE SOLUBILIZATION BY DETERGENT - USE OF BROMINATED PHOSPHOLIPIDS TO EVALUATE THE DETERGENT-INDUCED CHANGES IN CA-2+-ATPASE LIPID INTERACTION [J].

DEFORESTA, B ;

LEMAIRE, M ;

ORLOWSKI, S ;

CHAMPEIL, P ;

LUND, S ;

MOLLER, JV ;

MICHELANGELI, F ;

LEE, AG .

BIOCHEMISTRY, 1989, 28 (06) :2558-2567

[5] MICELLES OF 1-ALKYL GLUCOSIDE AND MALTOSIDE - ANOMERIC EFFECTS ON STRUCTURE AND INDUCED CHIRALITY [J].

FOCHER, B ;

SAVELLI, G ;

TORRI, G ;

VECCHIO, G ;

MCKENZIE, DC ;

NICOLI, DF ;

BUNTON, CA .

CHEMICAL PHYSICS LETTERS, 1989, 158 (06) :491-494

[6] A NEW SURFACTANT SERIES, THE N-ALKYLAMINO-1-DEOXYLACTITOLS - APPLICATION FOR EXTRACTION OF OP OPIATE RECEPTORS FROM FROG BRAIN [J].

GARELLICALVET, R ;

LATGE, P ;

RICO, I ;

LATTES, A ;

PUGET, A .

BIOCHIMICA ET BIOPHYSICA ACTA, 1992, 1109 (01) :55-58

[7]

HELENIUS A, 1975, BIOCHIM BIOPHYS ACTA, V424, P29

[8] LIGHT-HARVESTING PARTICLES ISOLATED FROM A BROWN ALGA, DICTYOTA-DICHOTOMA - A SUPRAMOLECULAR ASSEMBLY OF FUCOXANTHIN-CHLOROPHYLL-PROTEIN COMPLEXES [J].

KATOH, T ;

MIMURO, M ;

TAKAICHI, S .

BIOCHIMICA ET BIOPHYSICA ACTA, 1989, 976 (2-3) :233-240

[9]

LATGE P, 1992, NEW J CHEM, V16, P387

[10] SYNTHESIS OF LONG-CHAIN N-ALKYLLACTYLAMINES FROM UNPROTECTED LACTOSE A NEW SERIES OF NONIONIC SURFACTANTS [J].

LATGE, P ;

RICO, I ;

GARELLI, R ;

LATTES, A .

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 1991, 12 (3-4) :227-237

← 1 2 →