CHEMOENZYMATIC SYNTHESIS OF ALPHA-BICHIRAL SYNTHONS - APPLICATION TO THE PREPARATION OF CHIRAL EPOXIDES

被引：24

作者：

BESSE, P ^{[1
]}

VESCHAMBRE, H ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND,CHIM ORGAN BIOL LAB,CNRS,URA 485,F-63177 CLERMONT FERRAND,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)80239-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Microbiological reduction of 3-bromo-2-octanone and 3-azido-2-octanone led to all the stereoisomers of 3-bromo-2-octanol and 3-azido-2-octanol. Chiral 2,3-epoxyoctanes were prepared from the 3-bromo-2-octanols.

引用

页码：1271 / 1285

页数：15

共 18 条

[1] ARMANI E, 1984, TETRAHEDRON, V40, P1035
[2] BELAN A, 1986, J ORG CHEM, V52, P257
[3] SYNTHESIS OF THE PHEROMONE COMPONENTS OF THE GRAPE BORER XYLOTRECHUS-PYRRHODERUS BY MICROBIOLOGICAL REDUCTION OF AN ALPHA-DIKETONE
BELRHLID, R
FAUVE, A
VESCHAMBRE, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (13) : 3221 - 3223
[4] BELRHLID R, 1992, BIOCATALYSIS, V6, P319
[5] AZIDOCARBONYL COMPOUNDS .1. A NEW SYNTHESIS FOR CERTAIN SUBSTITUTED IMIDAZOLES FROM PHENACYL AZIDES
BOYER, JH
STRAW, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (18) : 4506 - 4508
[6] LACTOBACILLUS-KEFIR ALCOHOL-DEHYDROGENASE - A USEFUL CATALYST FOR SYNTHESIS
BRADSHAW, CW
HUMMEL, W
WONG, CH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (05) : 1532 - 1536
[7] STEREOSPECIFIC ANGULAR ALKYLATION - NEW APPLICATION OF CLAISEN REARRANGEMENT
BURGSTAHLER, A
NORDIN, IC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (01) : 198 - +
[8] USE OF BIOLOGICAL-SYSTEMS FOR THE SYNTHESIS OF CHIRAL MOLECULES .5. MICROBIOLOGICAL REDUCTION OF ACYCLIC BETA-DIKETONES
FAUVE, A
VESCHAMBRE, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (22) : 5215 - 5219
[9] MICROBIAL TRANSFORMATIONS .12. REGIOSPECIFIC AND ASYMMETRIC OXIDATION OF THE REMOTE DOUBLE-BOND OF GERANIOL
FOURNERON, JD
ARCHELAS, A
FURSTOSS, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (19) : 4686 - 4689
[10] VICINAL DIOL CYCLIC SULFATES - LIKE EPOXIDES ONLY MORE REACTIVE
GAO, Y
SHARPLESS, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) : 7538 - 7539

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