SAMARIUM DIIODIDE-PROMOTED REDUCTIVE CLEAVAGE OF CARBON-SULFUR BONDS - A NOVEL STEREOSELECTIVE GENERATION OF FUNCTIONALIZED VINYLSAMARIUM SPECIES AND SYNTHESIS OF BETA-THIOBUTENOLIDES

被引：34

作者：

HOJO, M ^{[1
]}

HARADA, H ^{[1
]}

YOSHIZAWA, J ^{[1
]}

HOSOMI, A ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Alkoxycarbonyl)ketene dithioacetals are cleanly reduced by SmI2 to provide a new and efficient method for the stereoselective generation of the corresponding novel highly functionalized vinylsamarium species which react with a proton, allyl bromide, and aldehydes to give the corresponding reduction products, allylation products, and beta-thiobutenolides, respectively.

引用

收藏

页码：6541 / 6542

页数：2

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