SELECTIVE OXIDATION OF N-HEXANE OVER A TITANIUM SILICATE MOLECULAR-SIEVE WITH MEL STRUCTURE

被引：24

作者：

REDDY, JS

SIVASANKER, S

RATNASAMY, P

机构：

[1] Catalysis Division, National Chemical Laboratory, Pune

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 70卷 / 03期

关键词：

D O I：

10.1016/0304-5102(91)80128-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective oxidation of n-hexane to secondary alcohols and ketones has been carried out with hydrogen peroxide using TS-2, a titanium silicate molecular sieve, as the catalyst. TS-2 is found to be highly selective in the oxidation of alkanes. The influence of various parameters, such as the Ti/(Si + Ti) ratio of TS-2, its concentration, the temperature of the reaction, the feed ratio (n-C6:H2O2), the nature of the solvent and the substrate (reactant) size and shape, on the activity and selectivity in the oxyfunctionalization reaction are reported.

引用

页码：335 / 342

页数：8