NEW ARYL DIHYDROGERMYLLITHIUM COMPOUNDS

被引：17

作者：

CASTEL, A ^{[1
]}

RIVIERE, P ^{[1
]}

SATGE, J ^{[1
]}

DESOR, D ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,CHIM ORGANOMINERAUX LAB,CNRS,URA 477,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 433卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)80129-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new aryldihydrogermyllithium complexes RH2GeLi (R = Ph, Mes) are prepared, in good yields, by metallation of the parent trihydrogermane with t-butyllithium in THF. They are characterized by alkylation reactions with MeI. Some germylation reactions are reported: they lead to the formation of new functional aryldihydrogermanes and aryldigermanes by a nucleophilic substitution. These aryldihydrogermyllithium complexes react also with acyl chlorides RCOCl (R = Ph, Mes) to give new diacyl- and triacyl-germanes. These easily add to the carbonyl group of aromatic aldehydes, thereby giving the corresponding alpha-germyl alcohols.

引用

页码：49 / 61

页数：13

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