ELECTRONIC EFFECTS ON CROWN-ETHER CONFORMATION - X-RAY CRYSTAL-STRUCTURE AND C-13 NMR-STUDY IN SOLUTION AND THE SOLID-PHASE OF 4-NITROBENZO-9-CROWN-3 ETHER

被引：11

作者：

BUCHANAN, GW

DRIEGA, AB

MOGHIMI, A

BENSIMON, C

机构：

[1] Carleton Univ, Ottawa, Ont

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1994年 / 72卷 / 08期

关键词：

D O I：

10.1139/v94-223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray crystal structure of the title material has been determined and the results are compared to previous findings for benzo-9-crown-3 itself. The C-13 NMR spectrum in solution has been unambiguously assigned using COSY and HETCOR methods. The solid phase C-13 spectrum has been obtained and the 7,10-d(4) derivative has been examined to aid in spectral assignments.

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页码：1764 / 1768

页数：5

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