ALKYLATIONS OF ALPHA-METHYL SUBSTITUTED BETA-DIKETONES THROUGH THEIR CU(II) COMPLEXES - PREPARATION OF STERICALLY CONGESTED BETA-DIKETONES

被引：16

作者：

LLORIS, ME ^{[1
]}

MARQUET, J ^{[1
]}

MORENOMANAS, M ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT CHEM,E-08193 BARCELONA,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)88524-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenybutane-1, 3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested beta-diketones have been prepared.

引用

页码：7489 / 7492

页数：4

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