EXCHANGE OF ORGANOIMIDO GROUPS AT A MONONUCLEAR TITANIUM CENTER AND A CRYSTALLOGRAPHIC EVALUATION OF THE RELATIVE STRUCTURAL INFLUENCES OF THE NBU(T), NC(6)H(4)ME-4 AND NC6H4NO2-4 LIGANDS

被引：39

作者：

COLLIER, PE ^{[1
]}

DUNN, SC ^{[1
]}

MOUNTFORD, P ^{[1
]}

SHISHKIN, OV ^{[1
]}

SWALLOW, D ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 22期

关键词：

D O I：

10.1039/dt9950003743

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tert-butylimido complex [Ti(NBu(t))Cl-2(py)(3)] 1a (py = pyridine) undergoes exchange reactions of the NBu(t) ligand with arylamines RNH(2) to form the arylimido derivatives [Ti(NR)Cl-2(py)(3)] (R = C(6)H(4)Me-4 1b, C6H4NO2-4 1c or C(6)H(3)Me(2)-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d(0), six-co-ordinated organoimido complexes.

引用

页码：3743 / 3745

页数：3

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