SYNTHESIS AND X-RAY STRUCTURE OF AN SP(2) SILICON STABILIZED BY 2 INTRAMOLECULAR COORDINATIONS

被引：34

作者：

BRELIERE, C ^{[1
]}

CARRE, F ^{[1
]}

CORRIU, R ^{[1
]}

MAN, MWC ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,HETEROCHIM & AMINOACIDES LAB,CNRS,URA 1097,F-34095 MONTPELLIER 05,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 20期

关键词：

D O I：

10.1039/c39940002333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of bis[8-(dimethylamino)naphthyl]dihydrosilane with iodine gives 2[L(2)SiH](+)l(8)(2-) {L= [8-(dimethylamino)naphthyl]}; the X-ray crystal structure determination shows a slightly distorted trigonal bipyramid around the silicon atom with apical NMe(2) ligands and short Si-N distances [2.06 and 2.08(1) Angstrom].

引用

页码：2333 / 2334

页数：2

共 28 条

[1]

ARYA P, 1989, ANGEW CHEM INT EDIT, V28, P1069

[2]

AUNER N, 1991, HETEROATOM CHEM, V2, P335

[3] THE PREPARATION AND OBSERVATION BY SI-29 NMR-SPECTROSCOPY OF SIMPLE, ACYCLIC, 5-CO-ORDINATE SILICON SALTS [J].

BASSINDALE, AR ;

STOUT, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (21) :1387-1389

[4] 5-COORDINATE POTASSIUM DIHYDRIDOSILICATES - SYNTHESIS AND SOME ASPECTS OF THEIR REACTIVITY [J].

BECKER, B ;

CORRIU, RJP ;

GUERIN, C ;

HENNER, B ;

WANG, Q .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (02) :C25-C28

[5] HEXACOORDINATED SILICON SPECIES - A POSSIBLE MODEL FOR REACTION INTERMEDIATES .1. X-RAY DETERMINATION OF THE GEOMETRY IN THE SOLID-STATE [J].

BRELIERE, C ;

CARRE, F ;

CORRIU, RJP ;

POIRIER, M ;

ROYO, G ;

ZWECKER, J .

ORGANOMETALLICS, 1989, 8 (07) :1831-1833

[6] POSSIBILITY OF HEPTACOORDINATION AT SILICON - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF TRIS[8-(DIMETHYLAMINO)NAPHTHYL]SILANE AND TRIS[2-((DIMETHYLAMINO)METHYL)PHENYL]FLUOROSILANE [J].

BRELIERE, C ;

CARRE, F ;

CORRIU, RJP ;

ROYO, G ;

MAN, MWC ;

LAPASSET, J .

ORGANOMETALLICS, 1994, 13 (01) :307-314

[7]

BRELIERE C, 1990, 9TH INT S ORG CHEM E, P3

[8] TERTIARY ALCOHOLYSIS OF CHLOROSILANES VIA TETRACOORDINATE SILYLATED QUATERNARY AMMONIUM INTERMEDIATES [J].

CHU, HK ;

JOHNSON, MD ;

FRYE, CL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 271 (1-3) :327-336

[9] INTRAMOLECULAR BASE STABILIZATION OF SILICENIUM IONS - A NEW ROUTE TO SILICONIUM IONS [J].

CHUIT, C ;

CORRIU, RJP ;

MEHDI, A ;

REYE, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09) :1311-1313

[10]

CHUIT C, 1993, CHEM REV, V93, P1411

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