THE PHOTOCHEMICAL-SYNTHESIS OF POTENTIAL PYRETHROID COMPONENTS BY THE AZA-DI-PI-METHANE REARRANGEMENT OF BETA,GAMMA-UNSATURATED OXIME ACETATES

被引：7

作者：

ARMESTO, D ^{[1
]}

GALLEGO, MG ^{[1
]}

HORSPOOL, WM ^{[1
]}

机构：

[1] UNIV DUNDEE,DEPT CHEM,DUNDEE DD1 4HN,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97393-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The syntheses and photochemical reactions of oxime acetates of ethyl 4,4-dimethyl-5-oxopent-2-enoate and ethyl 2,4,4-trimethyl-5-oxo-2-enoate are described. The former compound undergoes EZ of the CC bond while the latter rearranges by the aza-di-π-methane reaction to afford a cyclopropane derivative. © 1990.

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页码：2475 / 2478

页数：4

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