SELECTIVE REDUCTION OF ALKYNES BY THE REAGENT SMI2 - TRANSITION-METAL CATALYSTS - PROTON DONORS

被引：16

作者：

INANAGA, J ^{[1
]}

YOKOYAMA, Y ^{[1
]}

BABA, Y ^{[1
]}

YAMAGUCHI, M ^{[1
]}

机构：

[1] KYUSHU UNIV 33,DEPT CHEM,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

D O I：

10.1016/0040-4039(91)80083-I

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynes were selectively reduced to cis-olefins under mild conditions by Sml2 in admixture with first-row transition metal catalysts and appropriate proton donors, in which the corresponding transition metal hydrides are presumed as the reactive species. The conditions also effected the conversion of 1,6-diynes to the corresponding five-membered carbocycles.

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页码：5559 / 5562

页数：4

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