STEREOSELECTIVE EPOXIDATION OF CHIRAL ELECTRON-POOR GAMMA-AMINOOLEFINS

被引：33

作者：

REETZ, MT

LAUTERBACH, EH

机构：

[1] Fachbereich Chemie der Universität, 3550 Marburg, Hans-Meerwein-Strasse

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

AMINO ACIDS; GAMMA-AMINOOLEFINS; EPOXIDATION; DIASTEREOSELECTIVITY;

D O I：

10.1016/0040-4039(91)80016-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral alpha,beta-unsaturated compounds 3 and 8, prepared from amino acids 1, undergo stereoselective epoxidation reactions using tBuOOH/KOtBu in THF/NH3.

引用

页码：4477 / 4480

页数：4

共 25 条

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[22] REETZ MT, IN PRESS ANGEW CHEM
[23] ROHRIG D, 1991, THESIS MARBURG
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[25] ENANTIOMERICALLY PURE ALPHA',BETA'-DIFUNCTIONALIZED ALPHA,BETA-ENONES BY HIGHLY DIASTEREOSELECTIVE NUCLEOPHILIC ALKENOYLATION OF CHIRAL ALDEHYDES
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[J]. TETRAHEDRON LETTERS, 1989, 30 (22) : 2919 - 2922

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