THE CRYSTAL-CHEMISTRY OF OXOVANADATES - GAMMA-COV2O6 AND MNV2O6

被引：37

作者：

MULLERBUSCHBAUM, H

KOBEL, M

机构：

[1] Institut für Anorganische Chemie der Christian-Albrechts-Universität, W-2300 Kiel

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1991年 / 176卷 / 01期

关键词：

D O I：

10.1016/0925-8388(91)90008-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The crystal structures of gamma-CoV2O6 (I) and MnV2O6 (II) were examined by means of single-crystal X-ray crystallography. I crystallizes with the NiV2O6 structure, space group C(i)1-P1BAR; a = 7.164 angstrom; b = 8.872 angstrom; c = 4.806 angstrom; alpha = 90.29-degrees, beta = 93.66-degrees; gamma = 102.05-degrees; Z = 3. II is of the Brannerite type, space group C2h3-C2/m; a = 9.289 angstrom; b = 3.535 angstrom; c = 6.763 angstrom; beta = 112.64-degrees; Z = 2. The crystal structures and their relationships to each other are discussed.

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页码：39 / 46

页数：8

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