SYNTHESIS AND STRUCTURE OF A [(1,2-PHENYLENEDIOXY)BORYL]IRIDIUM HYDRIDE COMPLEX - A MODEL SYSTEM FOR STUDYING CATALYTIC HYDROBORATION

被引：151

作者：

KNORR, JR ^{[1
]}

MEROLA, JS ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 12期

关键词：

D O I：

10.1021/om00162a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition of the B‒H bond in (1,2-phenylenedioxy)borane to Ir(COE)(PMe3)3CI (COE = cyclooctene) produces mer-Ir(H)(BO2C6H4)(CI)(PMe3), 1, which was characterized by single crystal X-ray diffraction. Compound 1 reacts with alkynes to form vinyliridium complexes and will catalyze the hydroboration of alkynes with (1,2-phenylenedioxy)borane. © 1990, American Chemical Society. All rights reserved.

引用

页码：3008 / 3010

页数：3

共 15 条

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