SN[CO(CO)4]4, A BIFUNCTIONAL CATALYST OF THE HYDROFORMYLATION-ACETALIZATION REACTION

被引：14

作者：

CABRERA, A ^{[1
]}

MORTREUX, A ^{[1
]}

PETIT, F ^{[1
]}

机构：

[1] UNIV SCI & TECH LILLES FLANDRES ARTOIS,ECOLE NATL SUPER CHIM LILLE,CHIM ORGAN APPL LAB,CNRS,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1988年 / 47卷 / 01期

关键词：

Catalysts--Performance - Metallic Compounds;

D O I：

10.1016/0304-5102(88)85067-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The authors carried out a study of the behavior of the metallic cluster Sn[Co(CO)4]4 as a catalyst of olefin hydroformylation. In this study, a comparison was made of the hydroformylation of hexene-1 using both Co2(CO)8 and the tin-cobalt cluster Sn[Co(CO)4]4 as catalysts. It was found that, while the cluster showed a lower hydroformylation activity than the other catalyst, only the cluster is capable of catalyzing an acetalization reaction together with hydroformylation, thus confirming its bifunctional character.

引用

页码：11 / 15

页数：5

共 13 条

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