NEW CHIRAL MODIFIERS FOR THE ENANTIOSELECTIVE HYDROGENATION OF ETHYL PYRUVATE OVER PT/AL2O3 CATALYSTS

被引：49

作者：

WANG, GZ

HEINZ, T

PFALTZ, A

MINDER, B

MALLAT, T

BAIKER, A

机构：

[1] UNIV BASEL,INST ORGAN CHEM,CH-4056 BASEL,SWITZERLAND

[2] ETH ZURICH,DEPT CHEM ENGN & IND CHEM,CH-8092 ZURICH,SWITZERLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic quantities of structurally simple chiral amino alcohols such as 2-(1-pyrrolidinyl)-1-(1-naphthyl)ethanol can induce enantioselectivities of up to 75% e.e. in the hydrogenation of ethyl pyruvate over Pt/Al2O3 catalysts.

引用

页码：2047 / 2048

页数：2

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