STEREOISOMERIC FLAVOR COMPOUNDS .53. CHIRAL COMPOUNDS OF ESSENTIAL OILS .8. STEREODIFFERENTIATION OF LINALOOL USING MULTIDIMENSIONAL GAS-CHROMATOGRAPHY

被引：25

作者：

SCHUBERT, V ^{[1
]}

MOSANDL, A ^{[1
]}

机构：

[1] UNIV FRANKFURT,INST LEBENSMITTELCHEM,ROBERT MAYER STR 7-9,W-6000 FRANKFURT,GERMANY

来源：

PHYTOCHEMICAL ANALYSIS | 1991年 / 2卷 / 04期

关键词：

LINALOOL; CHIRAL RESOLUTION; STEREODIFFERENTIATION; MULTIDIMENSIONAL GAS CHROMATOGRAPHY; ESSENTIAL OILS;

D O I：

10.1002/pca.2800020406

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper reports on the chiral evaluation of linalool as an additional criterion of authenticity of lavender oils, using enantioselective multidimensional gas chromatography with a column combination of Superox and heptakis(2,3,6-tri-O-ethyl)-beta-cyclodextrin in OV-1701-vi. This method is extended to some other valuable spice oils-investigations on the enantiomeric distribution of their linalool content are discussed in terms of quality control of essential oil.

引用

页码：171 / 174

页数：4

共 19 条

[1] Bernreuther A., Christoph N., Schreier P., Determination of the enantiomeric compositin of γ‐lactones in complex natural matrices using multidimensional capillary gas chromatography, J. Chromatogr., 481, pp. 363-367, (1989)
[2] Cornforth R.H., Cornforth J.W., Prelog V., Über die absolute Konfiguration des Linalools, eine Berichtigung, Justus Liebigs Annalen der Chemie, 634, pp. 197-198, (1960)
[3] Guichard E., Kustermann A., Mosandl A., Chiral flavour compounds from apricots–distribution of γ‐lactone enantiomers and stereodifferentiation of dihydroactinidio‐lide using multidimensional gas chromatography, J. Chromatogr., 498, pp. 396-401, (1990)
[4] Konig W.A., Modifizierte Cyclodextrine als chirale Trennphasen in der Gaschromatographie, Kontakte (Darmstadt), 2, pp. 3-14, (1990)
[5] Konig W.A., Krebber R., Evers P., Bruhn G., Stereochemical analysis of constituents of essential oils and flavor compounds by enantioselective capillary gas chromatography, Journal of High Resolution Chromatography, 13, pp. 328-332, (1990)
[6] Mosandl A., Schubert V., Stereoisomeric flavor compounds. XXXVII: Enantiomer separation of 1‐alken‐3‐yl esters and their chirality evaluation from essential oils using multidimensional gas chromatography (MDGC), Journal of Essential Oil Research, 2, pp. 121-132, (1990)
[7] Mosandl A., Schubert V., Stereoisomere Aromastoffe. XXXIX: Chirale Inhaltsstoffe ätherischer Öle (I), Stereodifferenzierung des Linalylacetats–ein neuer Weg zur Qualitätsbeurteilung des Lavendelöls, Z. Lebensm. Unters. Forsch., 190, pp. 506-510, (1990)
[8] Mosandl A., Hener U., Hagenauer-Hener U., Kustermann A., Stereoisomeric flavour compounds. XXXII: Direct enantiomer separation of chiral γ‐lactones from food and beverages by multidimensional gas chromatography, Journal of High Resolution Chromatography, 12, pp. 532-536, (1989)
[9] Mosandl A., Kustermann A., Hener U., Hagenauer-Hener U., Analytische Differenzierung natürlicher und naturidentischer γ‐Lactone in Lebensmitteln, Dtsch. Lebensm. Rundsch., 85, pp. 205-209, (1989)
[10] Mosandl A., Hener U., Kreis P., Schmarr H.-G., Chiral compounds of essential oils (II). Enantiomeric distribution of α‐pinene, β‐pinene and limonene in essential oils and extracts. Part 1: Rutaceae and gramineae, Flavour and Fragrance Journal, 5, pp. 193-199, (1990)

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