STEREOISOMERIC FLAVOR COMPOUNDS .53. CHIRAL COMPOUNDS OF ESSENTIAL OILS .8. STEREODIFFERENTIATION OF LINALOOL USING MULTIDIMENSIONAL GAS-CHROMATOGRAPHY

被引：25

作者：

SCHUBERT, V ^{[1
]}

MOSANDL, A ^{[1
]}

机构：

[1] UNIV FRANKFURT,INST LEBENSMITTELCHEM,ROBERT MAYER STR 7-9,W-6000 FRANKFURT,GERMANY

来源：

PHYTOCHEMICAL ANALYSIS | 1991年 / 2卷 / 04期

关键词：

LINALOOL; CHIRAL RESOLUTION; STEREODIFFERENTIATION; MULTIDIMENSIONAL GAS CHROMATOGRAPHY; ESSENTIAL OILS;

D O I：

10.1002/pca.2800020406

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper reports on the chiral evaluation of linalool as an additional criterion of authenticity of lavender oils, using enantioselective multidimensional gas chromatography with a column combination of Superox and heptakis(2,3,6-tri-O-ethyl)-beta-cyclodextrin in OV-1701-vi. This method is extended to some other valuable spice oils-investigations on the enantiomeric distribution of their linalool content are discussed in terms of quality control of essential oil.

引用

页码：171 / 174

页数：4

共 19 条

[11] Mosandl A., Fischer K., Hener U., Kreis P., Rettinger K., Schubert V., Stereoisomeric flavor compounds. XLVIII: Chirospecific analysis of natural flavors and essential oils, using multidimensional gas chromatography, J. Aric. Food Chem., 39, pp. 1131-1134, (1991)
[12] Nitz S., Kollmannsberger H., Drawert F., Über den Nachweis von nicht natürlichen Aromen in Fruchtschaumweinen. 2: Enantiomere γ‐Lactone in Passionsfrüchten und Passionsfruchtprodukten, Chem. Mikrobiol. Technol. Lebensm., 12, pp. 105-110, (1989)
[13] Ohloff G., Klein E., Die absolute Konfiguration des Linalools durch Verknüpfung mit dem Pinansystem, Tetrahedron, 18, pp. 37-42, (1962)
[14] Palm U., Askari C., Hener U., Jakob E., Mandler C., Gessner M., Mosandl A., Konig W.A., Evers P., Krebber R., Stereoisomere Aromastoffe. XLVII: Direkte chirospe‐zifische HRGC‐Analyse natürlicher δ‐Lactone, Z. Lebensm. Unters. Forsch., 192, pp. 209-213, (1991)
[15] Ravid U., Putievsky E., Bassat M., Ikan R., Weinstein V., Determination of the enantiomeric composition of natural and nature‐identical semiochemicals by <sup>1</sup>H NMR “Polarimetry”, Bioflavour '87, pp. 97-104, (1988)
[16] Rettinger K., Weber B., Mosandl A., Stereoisomere Aromastoffe. XLII: 2‐Methylbuttersäure–Enantio‐merenverteilung in Äpfeln und apfelhaltigen Lebensmitteln, Z. Lebensm. Unters. Forsch., 191, pp. 265-268, (1990)
[17] Rudmann A.A., Aldrich J.R., Chirality determinations for a tertiary alcohol. Ratios of linalool enantiomers in insects and plants, J. Chromatogr., 407, pp. 324-329, (1987)
[18] Schmarr H.-G., (1991)
[19] Schubert V., (1991)

← 1 2 →