EFFECT OF CARBON-DIOXIDE ON THE CATALYTIC-OXIDATION OF ETHYLENE OVER SILVER - REACTION-RATES AND COMPOSITION OF ADSORBED LAYER

被引：9

作者：

BULUSHEV, DA

KHASIN, AV

机构：

[1] Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 44卷 / 02期

关键词：

D O I：

10.1007/BF02073009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It has been found that when the reaction is carried out at pressures of the reaction mixture ranging from 1 to 400 Pa, small surface coverages by adsorbed oxygen, carbonate groups and irreversibly adsorbed carbon-containing particles are obtained. Rate relaxations are due to the concentration variations of adsorbed oxygen and CO3ads groups.

引用

页码：421 / 425

页数：5

共 8 条

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REACTION KINETICS AND CATALYSIS LETTERS, 1991, 44 (02) :439-444

[2]

KHASIN AV, 1985, DOKL AKAD NAUK SSSR+, V283, P1431

[3]

KHASIN AV, 1985, KINET KATAL, V26, P1500

[4]

KHASIN AV, 1985, KINET KATAL, V26, P1159

[5]

PARFENOV AN, 1985, DOKL AKAD NAUK SSSR+, V282, P388

[6]

PINAEVA LG, 1990, UNSEADY STATE PROCES, P391

[7]

Temkin M. I., 1985, PROBL KINET KATAL, V19, P73

[8] THE MECHANISM OF ETHYLENE EPOXIDATION [J].

VANSANTEN, RA ;

KUIPERS, HPCE .

ADVANCES IN CATALYSIS, 1987, 35 :265-321

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