EFFECT OF CARBON-DIOXIDE ON THE CATALYTIC-OXIDATION OF ETHYLENE OVER SILVER - CO2 ADSORPTION

被引：5

作者：

BULUSHEV, DA

KHASIN, AV

机构：

[1] Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 44卷 / 02期

关键词：

D O I：

10.1007/BF02073012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon dioxide adsorption on silver surface containing adsorbed oxygen has been studied. A quantitative description for this equilibrium is suggested. It is shown that the reactivity of adsorbed oxygen layer formed under ethylene oxidation with respect to CO2 is close to the properties of oxygen adsorbed on a clean silver surface.

引用

收藏

页码：439 / 444

页数：6

相关论文

共 9 条

[1] SURFACE CARBONATE ON AG(110) - AN X-RAY ABSORPTION FINE-STRUCTURE STUDY [J].

BADER, M ;

HILLERT, B ;

PUSCHMANN, A ;

HAASE, J ;

BRADSHAW, AM .

EUROPHYSICS LETTERS, 1988, 5 (05) :443-448

[2]

BARTEAU MA, 1981, J CHEM PHYS, V4, P4144

[3]

BOGDANCHIKOVA NE, 1990, KINET KATAL, V31, P151

[4] EFFECT OF CARBON-DIOXIDE ON THE CATALYTIC-OXIDATION OF ETHYLENE OVER SILVER - REACTION-RATES AND COMPOSITION OF ADSORBED LAYER [J].

BULUSHEV, DA ;

KHASIN, AV .

REACTION KINETICS AND CATALYSIS LETTERS, 1991, 44 (02) :421-425

[5] INFLUENCE OF CARBON-DIOXIDE ON THE POSITION OF OXYGEN-ADSORPTION EQUILIBRIUM ON SILVER [J].

BULUSHEV, DA ;

KHASIN, AV .

REACTION KINETICS AND CATALYSIS LETTERS, 1988, 36 (02) :455-460

[6] EFFECT OF CARBON-DIOXIDE ON THE CATALYTIC-OXIDATION OF ETHYLENE OVER SILVER - KINETIC REACTION MODEL ACCOUNTING FOR THE MODIFICATION OF CATALYST SURFACE BY CARBONATE GROUPS [J].

BULUSHEV, DA ;

KHASIN, AV .

REACTION KINETICS AND CATALYSIS LETTERS, 1991, 44 (02) :463-468

[7] ADSORPTION STUDIES ON CATALYSTS UNDER UHV HV CONDITIONS .1. OXYGEN-ADSORPTION ON ALUMINA SUPPORTED SILVER [J].

DEAN, M ;

BOWKER, M .

APPLIED SURFACE SCIENCE, 1988, 35 (01) :27-40

[8]

KHASIN AV, 1985, DOKL AKAD NAUK SSSR+, V283, P1431

[9]

KHASIN AV, 1985, KINET KATAL, V26, P1159