METAL-ASSISTED REACTIONS .21. EPOXIDATION OF ALKENES CATALYZED BY MANGANESE-PORPHYRINS - THE EFFECTS OF VARIOUS OXIDATIVELY-STABLE LIGANDS AND BASES

被引：51

作者：

GONSALVES, AMDR

JOHNSTONE, RAW

PEREIRA, MM

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

[2] UNIV COIMBRA,DEPT QUIM,P-3000 COIMBRA,PORTUGAL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 03期

关键词：

D O I：

10.1039/p19910000645

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Porphyrin-catalysed epoxidation of alkenes with hydrogen peroxide has been shown to occur in the presence of non-oxidisable ligands and bases whereas previous work has suffered from destruction of base and ligand with concomitant excessive use of oxidant. The advantageous use of adducts of hydrogen peroxide is described.

引用

页码：645 / 649

页数：5

共 23 条

[21] TRIPHENYLPHOSPHINE OXIDE-HYDROGEN PER OXIDE ADDUCT [J].