ON THE NATURE OF NON-FARADAIC CATALYSIS ON METAL-ELECTRODES

被引：13

作者：

SOBYANIN, VA

BELYAEV, VD

机构：

[1] Boreskov Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 51卷 / 02期

关键词：

D O I：

10.1007/BF02069080

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Non-Faradaic change of the rate of catalytic oxidation on polarization of the catalyst electrode deposited on a solid oxygen-conducting electrolyte has been shown to result from a chain reaction mechanism involving electrochemically generated oxygen species.

引用

收藏

页码：373 / 382

页数：10

相关论文

共 10 条

[1] THE EFFECT OF ELECTROCHEMICAL OXYGEN PUMPING ON THE RATE OF CO OXIDATION ON AU ELECTRODE-CATALYST [J].

MARINA, OA ;

SOBYANIN, VA .

CATALYSIS LETTERS, 1992, 13 (1-2) :61-69

[2] MECHANISM OF THE ELECTROCATALYTIC REDUCTION OF OXYGEN IN A TUBULAR SOLID OXIDE ELECTROLYTE FLOW REACTOR [J].

NGUYEN, BC ;

RINCONRUBIO, LM ;

MASON, DM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (09) :1860-1869

[3]

PERFILIEV MV, 1988, HIGH TEMPERATURE GAS

[4] CATALYSIS - ELECTROCHEMICAL PROMOTION [J].

PRITCHARD, J .

NATURE, 1990, 343 (6259) :592-593

[5] ON THE ORIGIN OF THE NON-FARADAIC ELECTROCHEMICAL MODIFICATION OF CATALYTIC ACTIVITY (NEMCA) PHENOMENA - OXYGEN ISOTOPE EXCHANGE ON PT ELECTRODE IN CELL WITH SOLID OXIDE ELECTROLYTE [J].

SOBYANIN, VA ;

SOBOLEV, VI ;

BELYAEV, VD ;

MARINA, OA ;

DEMIN, AK ;

LIPILIN, AS .

CATALYSIS LETTERS, 1993, 18 (1-2) :153-164

[6] OXYGEN ISOTOPE EXCHANGE OVER A PT ELECTRODE IN A CELL WITH SOLID OXIDE ELECTROLYTE [J].

SOBYANIN, VA ;

SOBOLEV, VI ;

BELYAEV, VD ;

DEMIN, AK ;

MARINA, OA .

REACTION KINETICS AND CATALYSIS LETTERS, 1992, 47 (02) :327-332

[7] ELECTRODE POLARIZATION AT THE AU, O2 (G) YTTRIA STABILIZED ZIRCONIA INTERFACE .1. THEORETICAL CONSIDERATIONS OF REACTION MODEL [J].

VANHASSEL, BA ;

BOUKAMP, BA ;

BURGGRAAF, AJ .

SOLID STATE IONICS, 1991, 48 (1-2) :139-154

[8] DEPENDENCE OF CATALYTIC RATES ON CATALYST WORK FUNCTION [J].

VAYENAS, CG ;

BEBELIS, S ;

LADAS, S .

NATURE, 1990, 343 (6259) :625-627

[9] NON-FARADAIC ELECTROCHEMICAL MODIFICATION OF CATALYTIC ACTIVITY - A STATUS-REPORT [J].

VAYENAS, CG ;

BEBELIS, S ;

YENTEKAKIS, IV ;

LINTZ, HG .

CATALYSIS TODAY, 1992, 11 (03) :303-438

[10] THE EFFECT OF ELECTROCHEMICAL OXYGEN PUMPING ON THE STEADY-STATE AND OSCILLATORY BEHAVIOR OF CO OXIDATION ON POLYCRYSTALLINE PT [J].

YENTEKAKIS, IV ;

VAYENAS, CG .

JOURNAL OF CATALYSIS, 1988, 111 (01) :170-188