HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF K(3)SB(3)A(2)O(14)CENTER-DOT-5H(2)O (A=P, AS)

被引：4

作者：

AN, YL ^{[1
]}

FENG, SH ^{[1
]}

XU, YH ^{[1
]}

YUE, Y ^{[1
]}

机构：

[1] ACAD SINICA,WUHAN INST PHYS,WUHAN 430071,PEOPLES R CHINA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 05期

关键词：

D O I：

10.1039/jm9950500773

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

K(3)Sb(3)A(2)O(14) . 5H(2)O (A=P, As) were synthesized by use of a hydrothermal method, and the synthesis conditions are discussed in detail. Both phases were characterized by various techniques including scanning electron microscopy, XRD, XPS, P-31 MAS NMR, IR, DTA-TG. The unit-cell parameters for K3Sb3P2O14 . 5H(2)O and K3Sb3As2O14 . 5H(2)O are slightly smaller than those for the corresponding phases synthesized by solid-state reactions.

引用

页码：773 / 776

页数：4