THE OXOVANADIUM-ORGANOPHOSPHONATE SYSTEM - COMPLEX CLUSTER STRUCTURES [(VO)(6)(TBUPO(3))(8)CL], [(VO)(4)(PHP(O)(2)OP(O)(2)PH)(4)CL](-), AND [V18O25(H2O)(2)(PHPO(3))(20)CL-4](4-) WITH ENCAPSULATED CHLORIDE ANIONS PREPARED FROM SIMPLE PRECURSORS

被引：101

作者：

SALTA, J ^{[1
]}

CHEN, Q ^{[1
]}

CHANG, YD ^{[1
]}

ZUBIETA, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1002/anie.199407571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simply heating a suspension of [Ph4P][VO2Cl2] and tBuPO3H2 in acetonitrile in a sealed tube to 100°C gave the first of the three title compounds as dark green crystals. The structure of this compound (shown on the right) could not have a more pleasing simplicity. Relatively minor changes in the starting materials led to other, more complicated products. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：757 / 760

页数：4

共 28 条

[1] SYNTHESIS AND STRUCTURE OF AN OXOVANADIUM(V)ORGANOPHOSPHONATE CLUSTER ENCAPSULATING A CHLORIDE-ION - [CLV7O12(O3PC6H5)(6)](2-) [J].