DIMERIC MN(III)-TETRAARYLPORPHYRINS AS CATALYSTS FOR H2O2-PROMOTED OLEFIN EPOXIDATION

被引：18

作者：

BANFI, S

MONTANARI, F

POZZI, G

QUICI, S

机构：

[1] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

[2] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

[3] UNIV STRASBOURG 1,CTR NEUROCHIM,CHIM SUBSTANCES NAT LAB,CNRS,F-67084 STRASBOURG,FRANCE

来源：

TETRAHEDRON | 1994年 / 50卷 / 30期

关键词：

D O I：

10.1016/S0040-4020(01)85369-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of dimeric Mn(III)-tetraarylporphyrins able to catalyze olefin epoxidation is reported. In the presence of one equivalent of lipophilic bidentate ligand 3 the efficiency of some of these catalysts is among the highest reported to now in 30% H2O2-promoted epoxidation (up to 1500 overall catalytic cycles). Slightly better results were obtained replacing 3 with two equivalents of N-hexylimidazole 10.

引用

页码：9025 / 9036

页数：12

共 36 条

[21] IMIDAZOLATE ANION BRIDGED METALLOPORPHYRINS OF RELEVANCE TO A MODEL FOR CYTOCHROME-OXIDASE
LANDRUM, JT
REED, CA
HATANO, K
SCHEIDT, WR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (10) : 3232 - 3234
[22] INVESTIGATION OF THE SYNTHESIS OF ORTHO-SUBSTITUTED TETRAPHENYLPORPHYRINS
LINDSEY, JS
WAGNER, RW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (04) : 828 - 836
[23] ROTHEMUND AND ADLER-LONGO REACTIONS REVISITED - SYNTHESIS OF TETRAPHENYLPORPHYRINS UNDER EQUILIBRIUM CONDITIONS
LINDSEY, JS
SCHREIMAN, IC
HSU, HC
KEARNEY, PC
MARGUERETTAZ, AM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (05) : 827 - 836
[24] DEPENDENCE OF ELECTROCATALYSIS FOR OXYGEN REDUCTION BY ADSORBED DICOBALT COFACIAL PORPHYRINS UPON CATALYST STRUCTURE
LIU, HY
WEAVER, MJ
WANG, CB
CHANG, CK
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 145 (02): : 439 - 447
[25] A CHEMICAL APPROACH TOWARD PHOTOSYNTHETIC REACTION CENTER
MARUYAMA, K
OSUKA, A
[J]. PURE AND APPLIED CHEMISTRY, 1990, 62 (08) : 1511 - 1520
[26] METALLOPORPHYRINS AS VERSATILE CATALYSTS FOR OXIDATION REACTIONS AND OXIDATIVE DNA CLEAVAGE
MEUNIER, B
[J]. CHEMICAL REVIEWS, 1992, 92 (06) : 1411 - 1456
[27] HIGHLY EFFICIENT NAOCL OLEFIN EPOXIDATIONS CATALYZED BY IMIDAZOLE OR PYRIDINE TAILED MANGANESE PORPHYRINS UNDER 2-PHASE CONDITIONS - INFLUENCE OF PH AND OF THE ANCHORED AXIAL LIGAND
MONTANARI, F
PENSO, M
QUICI, S
VIGANO, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (24) : 4888 - 4893
[28] MONTANARI F, 1992, REV HETEROATOM CHEM, V6, P94
[29] HIGH OXYGEN-EVOLVING ACTIVITY OF RIGIDLY LINKED MANGANESE(III) PORPHYRIN DIMERS - A FUNCTIONAL-MODEL OF MANGANESE CATALASE
NARUTA, Y
MARUYAMA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) : 3595 - 3596
[30] MECHANISM OF ALKENE EPOXIDATION BY IRON, CHROMIUM, AND MANGANESE HIGHER VALENT OXO-METALLOPORPHYRINS
OSTOVIC, D
BRUICE, TC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (07) : 314 - 320

← 1 2 3 4 →