NEW FINDINGS IN THE ELECTROPHILIC ADDITION OF HALOGENS TO OLEFINS

被引：42

作者：

HERGES, R

机构：

[1] Institut Für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, D-91054

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 01期

关键词：

ALKENE HALOGEN COMPLEXES; ALKYNE HALOGEN COMPLEXES; ELECTROPHILIC ADDITION; REACTION MECHANISMS;

D O I：

10.1002/anie.199500511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrophilic addition—so you thought you knew it all! Recent research into the title reaction shows that a reexamination of well‐established mechanisms by means of modern theoretical, analytica, and synthetic methods can be altogether worthwhile. For example. A. C. Legon et. al (Angew. Chem. Int. Ed. Engl. 1994, 33, 1512–1513) recently investigated the interactions between ethene and halogens with an FT microwave spectrometer equipped with a fast‐mixing nozzle. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：51 / 53

页数：3

相关论文

共 47 条

[1] LARGE FORMATION CONSTANT OF A TRANSIENT 1-1 DL-D(3)-TRISHOMOCUBYLIDENE-D(3)-TRISHOMOCUBANE.BR(2) CHARGE-TRANSFER COMPLEX - GENERAL IMPLICATIONS FOR THE MECHANISM OF ELECTROPHILIC BROMINATION OF OLEFINS [J].

BELLUCCI, G ;

BIANCHINI, R ;

CHIAPPE, C ;

GADGIL, VR ;

MARCHAND, AP .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (13) :3575-3577

[2] DIRECT EVIDENCE FOR BROMINE OLEFIN CHARGE-TRANSFER COMPLEXES AS ESSENTIAL INTERMEDIATES OF THE FAST IONIC ADDITION OF BROMINE TO CYCLOHEXENE [J].

BELLUCCI, G ;

BIANCHINI, R ;

AMBROSETTI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (08) :2464-2471

[3] THE SOLUTION BEHAVIOR OF THE ADAMANTYLIDENEADAMANTANE BROMINE SYSTEM - EXISTENCE OF EQUILIBRIUM MIXTURES OF BROMONIUM POLYBROMIDE SALTS AND A STRONG 1-1 MOLECULAR CHARGE-TRANSFER COMPLEX [J].

BELLUCCI, G ;

BIANCHINI, R ;

CHIAPPE, C ;

MARIONI, F ;

AMBROSETTI, R ;

BROWN, RS ;

SLEBOCKATILK, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) :2640-2647

[4]

BELLUCCI G, 1994, 12TH C PHYS ORG CHEM

[5] ROTATIONAL SPECTRUM OF THE GAS-PHASE DIMER OC...BRCL [J].

BLANCO, S ;

LEGON, AC ;

THORN, JC .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (10) :1365-1371

[6]

BLANCO S, IN PRESS J CHEM SOC

[7]

BLOEMINK H, 1994, ANGEW CHEM, V106, P157

[8] INTERMEDIATES IN THE GAS-PHASE REACTIONS OF ACETYLENE AND HALOGENS - THE IDENTIFICATION OF THE ACETYLENE-BRCL COMPLEX BY ROTATIONAL SPECTROSCOPY [J].

BLOEMINK, HI ;

HINDS, K ;

LEGON, AC ;

THORN, JC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (10) :1229-1230

[9] PROPERTIES OF THE INTERMEDIATE ETHYNE...CL2 FROM ITS ROTATIONAL SPECTRUM AND SOME GENERALIZATIONS FOR A SERIES B...CL2 [J].

BLOEMINK, HI ;

HINDS, K ;

LEGON, AC ;

THORN, JC .

CHEMICAL PHYSICS LETTERS, 1994, 223 (03) :162-166

[10] CAN THE PREEQUILIBRIUM MOLECULAR-COMPLEX IN A REACTIVE MIXTURE OF ETHENE AND CHLORINE BE CHARACTERIZED - AN ANSWER FROM ROTATIONAL SPECTROSCOPY [J].

BLOEMINK, HI ;

HINDS, K ;

LEGON, AC ;

THORN, JC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1321-1322

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