CONVENIENT PREPARATION AND USE OF POTASSIUM TETRACARBONYLFERRATE, K2[FE(CO)4], AN EASY-TO-HANDLE ANALOG OF THE COLLMAN REAGENT

被引：11

作者：

BABY, A

BRUNET, JJ

KINDELA, FB

NEIBECKER, D

机构：

[1] UNIV PAUL SABATIER,CNRS,UNITE 8241,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 20期

关键词：

D O I：

10.1080/00397919408010602

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient synthesis of K2[Fe(CO)4] from Fe(CO)5, KOH and tri(n-butyl)phosphine is described. This non-pyrophoric dianionic potassium ferrate displays the same reactivity as Na2[Fe(CO)4], provided that the reactions are conducted in DMAC or THF-DMAC solvent mixtures.

引用

页码：2827 / 2834

页数：8

共 13 条

[11] HYDROACYLATION OF ALKYL VINYL KETONES AND ACRYLIC ESTERS USING ORGANOTETRACARBONYLFERRATES - SYNTHESIS OF 1,4-DICARBONYL COMPOUNDS [J].