REACTIONS BETWEEN CERTAIN TRIALKOXYTUNGSTEN ALKYLIDYNE COMPLEXES AND CARBON-MONOXIDE - COMPETITIVE C-C BOND FORMATION LEADING TO ALKYNE OR KETENYL COMPLEXES

被引：19

作者：

CHISHOLM, MH ^{[1
]}

HO, D ^{[1
]}

HUFFMAN, JC ^{[1
]}

MARCHANT, NS ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ORGANOMETALLICS | 1989年 / 8卷 / 07期

关键词：

D O I：

10.1021/om00109a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1626 / 1636

页数：11

共 29 条

[1] TUNGSTEN-TUNGSTEN TRIPLE BOND .8. DINUCLEAR ALKOXIDES OF TUNGSTEN(III) AND STRUCTURAL CHARACTERIZATION OF HEXAISOPROPOXYBIS(PYRIDINE)DITUNGSTEN, THE 1ST COMPOUND WITH 4-COORDINATED TUNGSTEN ATOMS UNITED BY A TRIPLE BOND
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[2] TRANSFORMATION OF A TUNGSTEN(O) ALKYNE TO A TUNGSTEN(II) ALKYNE VIA VINYLIDENE, CARBYNE, AND KETENYL LIGANDS
BIRDWHISTELL, KR
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) : 4474 - 4483
[3] ELECTRONIC-STRUCTURE AND BONDING IN MONOCARBONYL ADDUCTS OF DIMOLYBDENUM AND DITUNGSTEN HEXAALKOXIDES - A THEORETICAL AND SPECTROSCOPIC INVESTIGATION INTO THE MECHANISM OF M-M AND C-O BOND ORDER REDUCTION
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[J]. ORGANOMETALLICS, 1986, 5 (10) : 2125 - 2138
[4] REACTIONS OF M-M TRIPLE BONDS WITH C-N TRIPLE BONDS - ADDUCT FORMATION (M = MO) AND METATHESIS (M = W) AS SEEN IN THE REACTIONS BETWEEN DIMETHYLCYANAMIDE AND HEXAALKOXIDES OF DIMOLYBDENUM AND DITUNGSTEN
CHISHOLM, MH
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (19) : 6162 - 6163
[5] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES - W2(MU-C2H2)REVERSIBLE2W=CH
CHISHOLM, MH
FOLTING, K
HOFFMAN, DM
HUFFMAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) : 6794 - 6805
[6] METAL METAL BONDS AND METAL-CARBON BONDS IN THE CHEMISTRY OF MOLYBDENUM AND TUNGSTEN ALKOXIDES
CHISHOLM, MH
[J]. POLYHEDRON, 1983, 2 (08) : 681 - 722
[7] REACTION BETWEEN BIS(BENZYL)TETRAISOPROPOXYDITUNGSTEN(W=W) AND BUT-2-YNE - W2(CH2PH)2(OPRI)4(ETA-2-C2ME2)2 AND W2(H)(OPRI)4(MU-CPH)(MU-C4ME4) - A TERMINAL METAL HYDRIDE WITH H-1-NMR RESONANCE 20 PPM DOWNFIELD OF ME4SI
CHISHOLM, MH
EICHHORN, BW
HUFFMAN, JC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (13) : 861 - 863
[8] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES - AN ALTERNATIVE TO THE METATHESIS REACTION M=M+-C=C--]2M=C
CHISHOLM, MH
HOFFMAN, DM
HUFFMAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) : 6806 - 6815
[9] EVIDENCE FOR EQUILIBRIA BETWEEN MU-ALKYNE AND ALKYLIDYNE COMPLEXES OF TUNGSTEN ALKOXIDES - [W2(OR)6(MU-C2R2')] REVERSIBLE MU2[(RO)3W=CR']
CHISHOLM, MH
CONROY, BK
HUFFMAN, JC
MARCHANT, NS
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (05): : 446 - 447
[10] CARBONYLATION OF (BUTO)3W=CNME2 AND (PRIO)3(PY)2W=CNME2 (PY = PYRIDINE) - 2 DIFFERENT MODES OF CARBON CARBON BOND FORMATION
CHISHOLM, MH
HUFFMAN, JC
MARCHANT, NS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) : 717 - 718

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