SMALL-ANGLE NEUTRON-SCATTERING FROM SULFONATE IONOMER SOLUTIONS .2. POLY-ELECTROLYTE EFFECTS IN POLAR-SOLVENTS

被引:33
作者
LANTMAN, CW
MACKNIGHT, WJ
SINHA, SK
PEIFFER, DG
LUNDBERG, RD
WIGNALL, GD
机构
[1] UNIV MASSACHUSETTS,AMHERST,MA 01003
[2] EXXON RES & ENGN CO,CORP RES SCI LABS,ANNANDALE,NJ 08801
[3] EXXON RES & ENGN CO,DIV PARAMINS,LINDEN,NJ 07036
[4] OAK RIDGE NATL LAB,NATL CTR SMALL ANGLE SCATTERING RES,OAK RIDGE,TN 37831
关键词
NEUTRONS - Scattering - ORGANIC COMPOUNDS - Solutions - POLYELECTROLYTES - SODIUM COMPOUNDS - SOLVENTS;
D O I
10.1021/ma00183a027
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Dimethylformamide solutions of lightly sulfonated polystyrene (SPS) ionomers have been studied. These SPS polymers possess a narrow molecular weight distribution and are in the form of sodium salts. A combination of reduced viscosity and small-angle neutron scattering (SANS) measurements reveal polyelectrolyte effects in these solutions. Mixed-labeling experiments were performed to provide a molecular basis for understanding these effects.
引用
收藏
页码:1344 / 1349
页数:6
相关论文
共 25 条
  • [1] de Gennes P.G., 1979, SCALING CONCEPTS POL
  • [2] MOLECULAR-WEIGHT DETERMINATION BY LIGHT SCATTERING
    DEBYE, P
    [J]. JOURNAL OF PHYSICAL AND COLLOID CHEMISTRY, 1947, 51 (01) : 18 - 32
  • [3] REMARKS ON POLYELECTROLYTE CONFORMATION
    DEGENNES, PG
    PINCUS, P
    VELASCO, RM
    BROCHARD, F
    [J]. JOURNAL DE PHYSIQUE, 1976, 37 (12): : 1461 - 1473
  • [4] Flory P.J., 1953, J PRINCIPLES POLYM C
  • [5] HARA M, 1986, POLYM PREPR AM CHEM, V27, P177
  • [6] ORDERED DISTRIBUTION OF ELECTRICALLY CHARGED SOLUTES IN DILUTE-SOLUTIONS
    ISE, N
    OKUBO, T
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (09) : 303 - 309
  • [7] THE ELECTROSTATIC FREE ENERGY OF POLYELECTROLYTE SOLUTIONS .1. RANDOMLY KINKED MACROMOLECULES
    KATCHALSKY, A
    LIFSON, S
    MAZUR, J
    [J]. JOURNAL OF POLYMER SCIENCE, 1953, 11 (05): : 409 - 423
  • [8] KIRSTE RG, 1982, SMALL ANGLE XRAY SCA
  • [9] SMALL-ANGLE NEUTRON-SCATTERING FROM SULFONATE IONOMER SOLUTIONS .2. POLY-ELECTROLYTE EFFECTS IN POLAR-SOLVENTS
    LANTMAN, CW
    MACKNIGHT, WJ
    SINHA, SK
    PEIFFER, DG
    LUNDBERG, RD
    WIGNALL, GD
    [J]. MACROMOLECULES, 1988, 21 (05) : 1344 - 1349
  • [10] LIGHT-SCATTERING-STUDIES OF IONOMER SOLUTIONS
    LANTMAN, CW
    MACKNIGHT, WJ
    PEIFFER, DG
    SINHA, SK
    LUNDBERG, RD
    [J]. MACROMOLECULES, 1987, 20 (05) : 1096 - 1101