DOUBLE-LAYER AND HYDRATION FORCES MEASURED BETWEEN SILICA SHEETS SUBJECTED TO VARIOUS SURFACE TREATMENTS

Force measurements between silica surfaces in aqueous solutions of NaCl are reported. Silica is prepared with one of three surface treatments: (i) flaming, (ii) exposure to steam for 150 h, and (iii) brief exposure to ammonia vapor. Analysis of electrical double-layer interactions indicates that the surface density of silanol groups increases with steam treatment, and that exposure to ammonia etches the surface slightly and renders it porous. The force at short range is dominated by a strong repulsion which is attributed to hydration of the surface. The hydration component of the force is not significantly affected by the surface treatments, nor by electrolyte concentration over the range investigated (up to 0.1 M). © 1993 Academic Press, Inc.