VINYL GLYCOSIDES IN OLIGOSACCHARIDE SYNTHESIS .1. A NEW LATENT-ACTIVE GLYCOSYLATION STRATEGY

被引:92
作者
BOONS, GJ
ISLES, S
机构
[1] School of Chemistry, The University of Birmingham, Edgbaston, Birmingham
关键词
D O I
10.1016/S0040-4039(00)73249-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We have developed a never latent-active glycosylation strategy. This glycosylation strategy is based on isomerisation of substituted allyl glycosides to give vinyl glycosides which can subsequently be used in a Lewis acid mediated glycosylation reaction. This approach will enable complex oligosaccharides of biological importance to be prepared in a highly convergent manner.
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页码:3593 / 3596
页数:4
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