PREPARATION AND STRUCTURAL CHARACTERIZATION OF DIOXANE-COORDINATED ALKALI-METAL BIS(TRIMETHYLSILYL)AMIDES

被引：56

作者：

EDELMANN, FT ^{[1
]}

PAUER, F ^{[1
]}

WEDLER, M ^{[1
]}

STALKE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 20期

关键词：

D O I：

10.1021/ic00046a028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unsolvated RbN(SiMe3)2 (1) and CsN(SiMe3)2 (2) have been prepared from rubidium and cesium metal respectively and excess hexamethyldisilazane. The molecular structures of the polymeric dioxane adducts NaN(SiMe3)2.C4H8O2 (3) and [MN(SiMe3)2.1.5C4H8O2].0.5C4H8O2 (4, M = Rb; 5, M = Cs) have been determined by low-temperature single-crystal X-ray diffraction.

引用

页码：4143 / 4146

页数：4

共 22 条

[1] STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)AMIDO)NEODYMIUM(III), ND[N(SI(CH3)3)2]3 [J].

ANDERSEN, RA ;

TEMPLETON, DH ;

ZALKIN, A .

INORGANIC CHEMISTRY, 1978, 17 (08) :2317-2319

[2] SYNTHESIS OF BIS[BIS(TRIMETHYLSILYL)AMIDO]IRON(II) - STRUCTURE AND BONDING IN MN[N(SIME3)2]2, FE[N(SIME3)2]2, CO[N(SIME3)2]2 - 2-COORDINATE TRANSITION-METAL AMIDES [J].

ANDERSEN, RA ;

FAEGRI, K ;

GREEN, JC ;

HAALAND, A ;

LAPPERT, MF ;

LEUNG, WP ;

RYPDAL, K .

INORGANIC CHEMISTRY, 1988, 27 (10) :1782-1786

[3] TRANSITION-METAL DIALKYLAMIDES AND DISILYLAMIDES [J].

BRADLEY, DC ;

CHISHOLM, MH .

ACCOUNTS OF CHEMICAL RESEARCH, 1976, 9 (07) :273-280

[4] LOW COORDINATION NUMBERS IN LANTHANIDE AND ACTINIDE COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF TRIS[BIS(TRIMETHYLSILYL)-AMIDO]LANTHANIDES [J].

BRADLEY, DC ;

GHOTRA, JS ;

HART, FA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (10) :1021-1027

[5]

BRADLEY DC, 1971, J AM CHEM SOC, V93, P2058

[6]

BRAUER G, 1981, HDB PRAPARATIVEN ANO, V2, P712

[7] SILYLAMIDO-DERIVATE VON EISEN UND KOBALT - BEITRAGE ZUR CHEMIE DER SILICIUM-STICKSTOFF-VERBINDUNGEN .32. [J].

BURGER, H ;

WANNAGAT, U .

MONATSHEFTE FUR CHEMIE, 1963, 94 (06) :1007-&

[8]

Burger H., 1964, MONATSH, V95, P1099

[9] BIS(DIOXANE) POTASSIUM BIS(TRIMETHYLSILYL)AMIDE [J].

DOMINGOS, AM ;

SHELDRIC.GM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (FEB15) :517-519

[10] CRYSTAL-STRUCTURE OF DIMERIC N-LITHIOHEXAMETHYLDISILAZANE ETHERATE, [(ET2O)LI[MU-N(SIME3)2]2LI(OET2)] [J].

ENGELHARDT, LM ;

MAY, AS ;

RASTON, CL ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1671-1673

← 1 2 3 →