PREPARATION AND STRUCTURAL CHARACTERIZATION OF DIOXANE-COORDINATED ALKALI-METAL BIS(TRIMETHYLSILYL)AMIDES

被引：56

作者：

EDELMANN, FT ^{[1
]}

PAUER, F ^{[1
]}

WEDLER, M ^{[1
]}

STALKE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 20期

关键词：

D O I：

10.1021/ic00046a028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unsolvated RbN(SiMe3)2 (1) and CsN(SiMe3)2 (2) have been prepared from rubidium and cesium metal respectively and excess hexamethyldisilazane. The molecular structures of the polymeric dioxane adducts NaN(SiMe3)2.C4H8O2 (3) and [MN(SiMe3)2.1.5C4H8O2].0.5C4H8O2 (4, M = Rb; 5, M = Cs) have been determined by low-temperature single-crystal X-ray diffraction.

引用

页码：4143 / 4146

页数：4

共 22 条

[11] UNUSUAL MOLECULAR-STRUCTURES OF SOME STERICALLY HINDERED LITHIUM AMIDES - ELECTRON-DIFFRACTION RESULTS ON GASEOUS [LI(N(SIME3)2)]2 AND X-RAY DATA ON CRYSTALLINE MONOMERIC LI(NHAR)(TMEDA) (AR = C6H2BUT3-2,4,6 TMEDA = ME2NCH2CH2NME2) [J].

FJELDBERG, T ;

HITCHCOCK, PB ;

LAPPERT, MF ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (13) :822-824

[12] 3-CO-ORDINATE SCANDIUM(III) AND EUROPIUM(III) - CRYSTAL AND MOLECULAR-STRUCTURES OF THEIR TRISHEXAMETHYLDISILYLAMIDES [J].

GHOTRA, JS ;

HURSTHOUSE, MB ;

WELCH, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (18) :669-670

[13] CRYSTAL-STRUCTURE OF N-SODIOHEXAMETHYLDISILAZANE, NA[N[SI (CH3) 3]2] [J].

GRUNING, R ;

ATWOOD, JL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 137 (01) :101-111

[14]

HARRIS DH, 1976, J ORGANOMET CHEM, V2, P13

[15] ASSOCIATION OF BIS(TRIMETHYLSILYL)AMIDOLITHIUM AND METHYL(TRIMETHYLSILANOLATO)BERYLLIUM IN SOLID STATE [J].

MOOTZ, D ;

ZINNIUS, A ;

BOTTCHER, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (05) :378-&

[16]

Mootz D., 1969, ANGEW CHEM, V81, P398

[17] ALKALI-METAL DERIVATIVES OF SULFINIMIDAMIDES - PREPARATION AND CRYSTAL-STRUCTURES [J].

PAUER, F ;

STALKE, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 418 (02) :127-145

[18]

Power P.P., 1989, COMMENTS INORG CHEM, V8, P177, DOI DOI 10.1080/02603598908035794

[19] MONONUCLEAR LITHIUM AMIDES USING A CROWN ETHER - X-RAY CRYSTAL-STRUCTURE OF LITHIUM "BIS(TRIMETHYLSILY)AMIDE.12-CROWN-4, [LIN(SIME3)2.12-CROWN-4] [J].

POWER, PP ;

XU, XJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (06) :358-359

[20]

Sheldrick G.M, 1986, SHELX 86

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