CARBOXYLATION OF INTACT BORANES

被引：4

作者：

FERRIE, DJ ^{[1
]}

MILLER, NE ^{[1
]}

机构：

[1] UNIV S DAKOTA,DEPT CHEM,VERMILLION,SD 57069

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 07期

关键词：

D O I：

10.1080/00945719408001390

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The carboxylation procedure using Me3NBH2N-C: to displace halogen on intact boranes was applied to make carboxylated derivatives of Me2BH2NMe2CH2BH2, Me3PBH3, and Me3NBH2CH2SiMe3. The retrograde reaction of decarboxylation to the halide, as well as two methods of forming carboxylic acid esters, are reported. Conversion of amide to nitrile function was also effected in two ways.

引用

页码：1139 / 1153

页数：15

共 8 条

[1] SYNTHESIS OF A NEW CLASS OF BORON CATIONS FROM 4-IODO-1,1,3,3-TETRAMETHYL-1,3-DIAZONIA-2,4-DIBORATOCYCLOPENTANE [J].