THE 1ST ALDEHYDE-DERIVED CRYSTALLINE GEMINAL DIOL LACKING INTERNAL ELECTRONIC STABILIZATION

被引：9

作者：

SMITH, DA

BAKER, D

RAHMAN, AFMM

机构：

[1] Department of Chemistry, The University of Toledo, Toledo, 436GB, Ohio

来源：

STRUCTURAL CHEMISTRY | 1991年 / 2卷 / 01期

关键词：

D O I：

10.1007/BF00673491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first stable crystalline geminal diol of an aldehyde lacking electron-withdrawing groups on the alpha-carbon was synthesized from D-sorbitol and characterized by H-1 and C-13 nuclear magnetic resonance (NMR) and single-crystal x-ray studies. Each hydroxyl is a donor for a single, unique intermolecular hydrogen bond. Only one hydroxyl acts as an acceptor. No intramolecular hydrogen bonding is observed in the crystal.

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页码：65 / 70

页数：6

相关论文

共 25 条

[1]

Bell R.P., 1966, ADV PHYS ORG CHEM, P1, DOI [10.1016/S0065-3160(08)60351-2, DOI 10.1016/S0065-3160(08)60351-2]

[2] The constitution of trimethylene sorbitol. [J].

Bourne, EJ ;

Wiggins, LF .

JOURNAL OF THE CHEMICAL SOCIETY, 1944, :517-521

[3]

BROWN GM, 1973, CRYST STRUCT COMMUN, V2, P107

[4] I-STRAIN AS A FACTOR IN THE CHEMISTRY OF RING COMPOUNDS [J].

BROWN, HC ;

FLETCHER, RS ;

JOHANNESEN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :212-221

[5]

Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV

[6] CRYSTAL AND MOLECULAR STRUCTURE OF 1-1 COMPLEX OF CHLORAL HYDRATE AND 7-BROMO-2,3-DIHYDRO-1-METHYL-5-PHENYL-1,4-BENZODIAZEPIN-2-ONE [J].

DUNPHY, RF ;

LYNTON, H .

CANADIAN JOURNAL OF CHEMISTRY, 1971, 49 (20) :3401-&

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF VITAMIN-B6 DERIVATIVES .1. PYRIDOXAL-PHOSPHATE HYDRATE AND PYRIDOXAL-PHOSPHATE METHYL HEMIACETAL [J].

FUJIWARA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (03) :863-871

[8]

GADRET PM, 1976, ACTA CRYSTALLOGR B, V32, P1406

[9] DISPERSION CORRECTIONS + CRYSTAL STRUCTURE REFINEMENTS [J].

IBERS, JA ;

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1964, 17 (06) :781-&

[10] SYNTHESIS, MOLECULAR-STRUCTURE, AND CHEMISTRY OF (P)-[(TRIS(2-AMINOETHYL)AMINE)(2-(DIHYDROXYMETHYL)-GLYCINATE)]COBALT(III)-ZINC TETRACHLORIDE WATER [J].

JACKSON, WG ;

MCLAUGHLIN, GM ;

SARGESON, AM ;

WATSON, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) :2426-2430