THE 1ST ALDEHYDE-DERIVED CRYSTALLINE GEMINAL DIOL LACKING INTERNAL ELECTRONIC STABILIZATION

被引：9

作者：

SMITH, DA

BAKER, D

RAHMAN, AFMM

机构：

[1] Department of Chemistry, The University of Toledo, Toledo, 436GB, Ohio

来源：

STRUCTURAL CHEMISTRY | 1991年 / 2卷 / 01期

关键词：

D O I：

10.1007/BF00673491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first stable crystalline geminal diol of an aldehyde lacking electron-withdrawing groups on the alpha-carbon was synthesized from D-sorbitol and characterized by H-1 and C-13 nuclear magnetic resonance (NMR) and single-crystal x-ray studies. Each hydroxyl is a donor for a single, unique intermolecular hydrogen bond. Only one hydroxyl acts as an acceptor. No intramolecular hydrogen bonding is observed in the crystal.

引用

页码：65 / 70

页数：6

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[11] SELECTIVE CONFORMATIONAL-CHANGES OF CYCLIC SYSTEMS .12. ENHANCED REACTIVITY OF 10 MEMBERED RING KETONES DUE TO TRANSANULAR STERIC COMPRESSION - HYDRATES AND HEMIKETALS FROM OXO-[2.2]METACYCLOPHANES [J].