OPTIMIZATION OF THE PROCEDURE FOR THE DETERMINATION OF ALKALI AND ALKALINE-EARTH ELEMENTS IN SEA-WATER BY SUPPRESSED ION CHROMATOGRAPHY

被引:17
作者
BETTI, M
GIOVANNONI, G
ONOR, M
PAPOFF, P
机构
[1] Institute of Instrumental Analytical Chemistry, CNR, Deparment of Chemistry, 56126 Pisa
来源
JOURNAL OF CHROMATOGRAPHY | 1991年 / 546卷 / 1-2期
关键词
D O I
10.1016/S0021-9673(01)93024-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An ion chromatographic procedure is described for the determination of alkali and alkaline-earth metal ions in sea water the molar ratios of which, referred to lithium, are: 2.5 . 10(4) for sodium, 5 . 10(2) for potassium and calcium, and 3.5 . 10(3) for magnesium. Lithium, potassium, magnesium and calcium are simultaneously analyzed after a 50-fold dilution, sodium is determined separately after a 2000-fold dilution. For all these elements, a dynamic range of several orders of magnitude and a R.S.D. varying from 0.2-2.2%, though typically lower than 1%, were found.
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页码:259 / 271
页数:13
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