RADICAL IONS OF POLYSILASTYRENE

被引：35

作者：

IRIE, S ^{[1
]}

OKA, K ^{[1
]}

IRIE, M ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

MACROMOLECULES | 1988年 / 21卷 / 01期

关键词：

IONS - Measurements - ORGANOMETALLICS - Spectroscopic Analysis;

D O I：

10.1021/ma00179a023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The absorption spectra of radical ions of polysilastyrene have been measured in rigid matrices at 77 K as well as in solution at room temperature by using gamma -irradiation and pulse radiolysis methods. The radical anion with lambda //m//a//x at 365 nm was observed in irradiated 2-methyltetrahydrofuran, while the radical cation with two absorption bands at 358 and 2000 nm was observed in irradiated n-butyl chloride at 77 K. Upon thermal annealing, the infrared band showed a blue shift to 1700 nm, which is attributed to the geometrical reorientation of pendant phenyl groups from the unrelaxed to relaxed dimer radical cation conformation.

引用

页码：110 / 112

页数：3

共 20 条

[11] FORMATION OF ION-PAIRS IN IRRADIATED CHARGE-TRANSFER SYSTEMS [J].