ENZYMATIC POLYMERIZATION OF AN UNACTIVATED DIOL DIACID SYSTEM

被引：61

作者：

BINNS, F ^{[1
]}

ROBERTS, SM ^{[1
]}

TAYLOR, A ^{[1
]}

WILLIAMS, CF ^{[1
]}

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4RJ,DEVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 08期

关键词：

D O I：

10.1039/p19930000899

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The polyesterification of adipic acid and butane-1,4-diol by a commercial lipase (Lipozyme IM-20) has been studied using a two-chamber reactor and molecular sieve as a dehydrating agent. The lower oligomeric products were identified and a low-dispersity polyester averaging 20 repeat units was produced.

引用

页码：899 / 904

页数：6

共 16 条

[1] POLYMERIZATION OF 10-HYDROXYDECANOIC ACID IN BENZENE WITH POLYETHYLENE GLYCOL-MODIFIED LIPASE
AJIMA, A
YOSHIMOTO, T
TAKAHASHI, K
TAMAURA, Y
SAITO, Y
INADA, Y
[J]. BIOTECHNOLOGY LETTERS, 1985, 7 (05) : 303 - 306
[2] ENZYMATIC-SYNTHESIS OF ALKYDS
GERESH, S
GILBOA, Y
[J]. BIOTECHNOLOGY AND BIOENGINEERING, 1990, 36 (03) : 270 - 274
[3] ENZYMATIC SYNTHESES OF ALKYDS .2. LIPASE-CATALYZED POLYTRANSESTERIFICATION OF DICHLOROETHYL FUMARATE WITH ALIPHATIC AND AROMATIC DIOLS
GERESH, S
GILBOA, Y
[J]. BIOTECHNOLOGY AND BIOENGINEERING, 1991, 37 (09) : 883 - 888
[4] ENZYMATIC OLIGOMERIZATION VERSUS LACTONIZATION OF OMEGA-HYDROXYESTERS
GUTMAN, AL
OREN, D
BOLTANSKI, A
BRAVDO, T
[J]. TETRAHEDRON LETTERS, 1987, 28 (44) : 5367 - 5368
[5] KLIBANOV AM, 1977, BIOTECHNOL BIOENG, V19, P1351, DOI 10.1002/bit.260190908
[6] STEREOSELECTIVE OLIGOMERIZATIONS CATALYZED BY LIPASES IN ORGANIC-SOLVENTS
MARGOLIN, AL
CRENNE, JY
KLIBANOV, AM
[J]. TETRAHEDRON LETTERS, 1987, 28 (15) : 1607 - 1610
[7] COMPARISON OF LIPASE-CATALYZED ESTERIFICATION IN SUPERCRITICAL CARBON-DIOXIDE AND IN NORMAL-HEXANE
MARTY, A
CHULALAKSANANUKUL, W
CONDORET, JS
WILLEMOT, RM
DURAND, G
[J]. BIOTECHNOLOGY LETTERS, 1990, 12 (01) : 11 - 16
[8] MORROW CJ, 1990, MATER RES SOC SYMP P, V174, P197
[9] NIKONOV VZ, 1988, POLYM SCI USSR, V30, P2606
[10] SYNTHESIS OF ESTER OLIGOMER BY ASPERGILLUS-NIGER LIPASE
OKUMURA, S
IWAI, M
TOMINAGA, Y
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1984, 48 (11): : 2805 - 2808

← 1 2 →