REACTIVITY OF COPPER(I) COMPLEXES CONTAINING VARIOUS TETRADENTATE TRIPODAL LIGANDS WITH MOLECULAR-OXYGEN

被引：30

作者：

UOZUMI, K ^{[1
]}

HAYASHI, Y ^{[1
]}

SUZUKI, M ^{[1
]}

UEHARA, A ^{[1
]}

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, KANAZAWA 92011, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 06期

关键词：

D O I：

10.1246/cl.1993.963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactivity of copper(I) complexes [Cu(L)]+ containing a series of tetradentate tripodal ligands, (6-methyl-2-pyridylmethyl)m(2-pyridylmethyl)(3-m)amine (m = 1, 2, or 3) with molecular oxygen was investigated in acetone at -70-degrees-C. It was found that the introduction of 6-methyl group(s) into pyridyl group(s) has significant influences on the stereochemistry and thermal stability of peroxo dicopper(II) complexes.

引用

页码：963 / 966

页数：4

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