CHEMICAL HOLE DIVING

被引：30

作者：

GREBER, T

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-14195 Berlin

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 222卷 / 03期

关键词：

D O I：

10.1016/0009-2614(94)00344-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The non-adiabatic reaction leading to the emission of exoelectrons during the adsorption of oxygen on lithium is exploited to estimate the time that elapses during the dissociation of the molecule. With a three-step model the exoemission probability is calculated. A comparison with experimentally observed probabilities predicts the reaction time to be 75 +/- 25 O2p hole lifetimes at the final O2p binding energy. The width of the exoelectron energy distribution reflects this hole lifetime. The absence of visible light emission (< 10(-10) photons/O2) is shown to be compatible with the model.

引用

页码：292 / 296

页数：5

共 15 条

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